Anthracite based activated carbon impregnated with HMTA as an effectiveness adsorbent could significantly uptake gasoline vapors.

In this study, we synthesized and employed the amine impregnated activated carbon as an efficacious adsorbent for uptaking gasoline vapor. For this regard, anthracite as activated carbon source and hexamethylenetetramine (HMTA) as amine were selected and utilized. Physiochemical characterization of made sorbents were evaluated and investigated using SEM, FESEM, BET, FTIR, XRD, zeta potential, and elemental analysis. The synthesized sorbents provided an excellent textural features as compared with the literature and other activated carbon based sorbents and impregnated with amine. Our findings also suggested that in addition to high surface area (up to 2150 m2 / g), the micro- meso pores created (Vmeso / V micro = 0.79 Cm 3 / g) surface chemistry may significantly affect the gasoline sorption capacity, which here the role of mesoporous is further highlighted. V meso for amine impregnated sample and free activated carbon was 0.89 and 0.31 Cm 3 / g, respectively. According to the results, the prepared sorbents have a potential capability in uptaking gasoline vapor and with line this, we report a high sorption capacity of 572.56 mg / g. After, four cycles used the sorbent had a high durability and about 99.11% of the initial uptake was maintained. Taking together the synthesized adsorbents as an activated carbon provided an excellent and unique features and enhanced gasoline uptake, therefore its applicability in uptaking gasoline vapor can be substantially considered.

Defect engineering-induced porosity in graphene quantum dots embedded metal-organic frameworks for enhanced benzene and toluene adsorption.

The emerging environmental issues necessitate the engineering of novel and well-designed nanoadsorbents for advanced separation and purification applications. Despite recent advances, the facile synthesis of hierarchical micro-mesoporous metal-organic frameworks (MOFs) with tuned structures has remained a challenge. Herein, we report a simple defect engineering approach to manipulate the framework, induce mesoporosity, and crease large pore volumes in MIL-101(Cr) by embedding graphene quantum dots (GQDs) during its self-assembly process. For instance, MIL-101@GQD-3 (Vmeso: 0.68 and Vtot: 1.87 cm3/g) exhibited 300.0% and 53.3% more meso and total pore volume compared to those of the conventional MIL-101 (Vmeso: 0.17 and Vtot: 1.22 cm3/g), respectively, resulting in 1.7 and 2.8 times greater benzene and toluene loading at 1 bar and 25 °C. In addition, we found that MIL-101@GQD-3 retained its superiority over a wide range of VOC concentrations and operating temperature (25-55 °C) with great cyclic capacity and energy-efficient regeneration. Considering the simplicity of the adopted technique to induce mesoporosity and tune the nanoporous structure of MOFs, the presented GQD incorporation technique is expected to provide a new pathway for the facile synthesis of advanced materials for environmental applications.